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Synthesis and Structural Characterization of Arsinoamide and its Metal Complexes (el. knyga) (skaityta knyga) | knygos.lt
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Aprašymas
The phosphinoamide chemistry has attracted a considerable attention owing to the structural diversity of the associated complexes. To further understand the properties of the P-N bond, Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)] through the deprotonation reaction of the corresponding aminophosphine with nBuLi. X-ray diffraction analyses indicated the presence of Li-P bonds (2.684 and 3.004 Ã ). In addition, the P-N bond length (1.672(2) Ã ) was relatively smaller than that of a single bond (mean value of 1.70).
- Autorius: Chen Xiao
- Leidėjas: Cuvillier
- ISBN-10: 373697034X
- ISBN-13: 9783736970342
- Formatas: 14.8 x 21 x 0.8 cm, minkšti viršeliai
- Kalba: Anglų
The phosphinoamide chemistry has attracted a considerable attention owing to the structural diversity of the associated complexes. To further understand the properties of the P-N bond, Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)] through the deprotonation reaction of the corresponding aminophosphine with nBuLi. X-ray diffraction analyses indicated the presence of Li-P bonds (2.684 and 3.004 Ã ). In addition, the P-N bond length (1.672(2) Ã ) was relatively smaller than that of a single bond (mean value of 1.70).
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