Chiral N,N'-Dioxide Amides in Asymmetric Catalysis (el. knyga) (skaityta knyga) | knygos.lt

Aprašymas

The success of the N,N'-dioxide amides and catalyst design not only represents a valuable addition to the toolkit of chiral ligand design but also enhances the stereo control of reactions with well-understood mechanisms. This enables unprecedented transformations to occur with high enantioselectivity. This book provides a complete narrative on the development, unique features, and efficiency of chiral N,N'-dioxide in a wide range of asymmetric transformations. It covers the historical development and evolution of chiral N,N'-dioxide amides, the application of chiral N,N'-dioxide amide organocatalysts in asymmetric synthesis, the detailed coordination chemistry and the structural aspects of N,N'-dioxide amides with various metals, and a comprehensive overview of their applications in different types of asymmetric reactions, including nucleophilic addition, oxidation/reduction, pericyclic reactions, and radical reactions. Moreover, it provides mechanistic insights into the catalytic processes facilitated by chiral N,N'-dioxide-metal complexes. This book is an invaluable reference for current methodologies and will inspire future innovations in chiral ligand design and application.